SYNTHESIS OF SP2 AND SP3 CARBON MATERIALS
Open Access
- Author:
- Keefer, Derek William
- Graduate Program:
- Chemistry
- Degree:
- Doctor of Philosophy
- Document Type:
- Dissertation
- Date of Defense:
- September 08, 2016
- Committee Members:
- John V. Badding, Dissertation Advisor/Co-Advisor
John V. Badding, Committee Chair/Co-Chair
Harry Allcock, Committee Member
Dave Allara, Committee Member
Vin Crespi, Outside Member - Keywords:
- Amorphous Carbon
Raman
IR
XRD
High Pressure
Chemical Vapor Deposition
Micro Plasma - Abstract:
- Carbon is the backbone of hundreds of products ranging from conductors to insulators and lubricants to machining tools. Diamond is the hardest material known and graphite is one of the softest, but there is a need for materials in between these two extremes. By taking advantage of the different pressure-dependent thermodynamic stabilities of graphite and diamond, the degree of sp2 and sp3 bonding in amorphous carbon materials can be varied. This control over bonding opens avenues for tuning properties such as electrical conductivity, hardness, and optical transmission. Two approaches to controlling sp3 and sp2 carbon formation have been studied. The first investigates techniques to deposit carbon at elevated pressures by high-pressure chemical vapor deposition. The second group of experiments involves high pressure synthesis techniques using a diamond anvil cell and developing precursors that will react at lower temperatures and pressures to give materials with sought after properties. This report is an investigation of the effect of high-pressure on the formation of amorphous carbon materials deposited by high-pressure chemical vapor deposition, dielectric breakdown plasma enhanced chemical vapor deposition, and laser induced plasma enhanced chemical vapor deposition. This report describes novel deposition and growth techniques such as high-pressure CVD of sp2 carbon wires in microcapillaries, with preliminary results showing increased sp3 bonding with the formation of a hydrogenated carbon material via plasma enhanced depositions. The second method approaches the tuning of sp2 and sp3 hybridization of carbon from the other direction of taking high pressure synthesis techniques and develop initial precursors that react at lower pressures forming an sp3 interconnected network. With pressure, amorphous carbons can also be made by compressing materials to the point where it is favorable for atoms to form new bonds. My focus is on developing a precursor that will react at lower pressure and temperatures than current fabrication techniques for forming ultra-hard materials such as diamond and cubic boron nitride. We have investigated precursors with highly unsaturated groups like cyanides and acetylenes because they have the potential to form new bonds. We have characterized these compounds with in situ Raman, IR, and XRD to track structural changes. Three different precursors have been studied to understand the effect of the starting structure on the reactivity and sp2/sp3 nature. By lowering the reaction pressure, bulk high pressure synthesis techniques could be used for more commercial applications.